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Photosensitized [4+2] cyclodimerizations of aromatic retinoids1

✍ Scribed by Karl-Heinz Pfoertner; Gerhard Englert; Peter Schoenholzer


Book ID
104203554
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
942 KB
Volume
44
Category
Article
ISSN
0040-4020

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The 9,10-dicyanoanthracene-photosensitized (DCA-photosensitized) electron-transfer reaction of 1-isopropylidene-2methylene-3,3-diphenylcyclobutane (3) gives a mixture of the [4 + 4] DCA adduct (5) and two [4 + 4] cyclodimers Scheme 1