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Photoresponsive Self-Assembly and Self-Organization of Hydrogen-Bonded Supramolecular Tapes

✍ Scribed by Shiki Yagai; Tomoyuki Iwashima; Keiki Kishikawa; Shoichiro Nakahara; Takashi Karatsu; Akihide Kitamura


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
776 KB
Volume
12
Category
Article
ISSN
0947-6539

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## Abstract A new strategy to effect photoinduced control over molecular self‐assembly is reported. This strategy uses the reversible __trans__–__cis__ photoisomerization of a novel azobenzene system, where the __trans__‐ and __cis__‐forms self‐assemble into dramatically different higher‐order stru

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An analysis is presented of the different contributions that ordered two-dimensional, mosaic-like sheets in the solid state. Its dicationic precursor also forms extended Ο€-Ο€give rise to the packing observed in the crystal structures of a wide range of bipyridinium-based molecular assemblies and stac