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Photoreduction of ferric-tetraphenylporphyrin in oxygen-containing solvents revealed by resonance Raman and absorption spectroscopy

โœ Scribed by Sergei N. Terekhov; Sergei G. Kruglik


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
334 KB
Volume
245
Category
Article
ISSN
0009-2614

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Alcohol-catalyzed photoreduction of iron
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Photoreduction of Fe"'(OEP) (2-MeIm) (OEP is octaethylporphyrin; Z-MeIm is 2-methylimidazole) was found to be catalyzed by a trace amount of MeOH present m CH& as a stabilizer. The absence of either 2-Melm or MeOH in the CH&l, solution of Fe'n(OEP)X (X is Cl-, Br-or I-) leads to no photoreduction. T