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Photoreduction of 5-bromouracil. Ionic and free-radical pathways

✍ Scribed by Swanson, Barry J.; Kutzer, J. Christopher; Koch, Tad H.

Book ID
127007791
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
432 KB
Volume
103
Category
Article
ISSN
0002-7863

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Free radical chain mechanism in the acetone-sensitized photolysis of 5-bromouracil and derivatives in alcohol-water mixtures
✍ Helmut GΓΆrner πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 845 KB

The acetone-sensitized photolysis of 5-bromouracil (BrU), 1-methyl-5-bromouracil (MeBrU) and 5-bromouridine (BrUd) in deoxygenated aqueous solution in the presence of alcohols was studied on irradiation at 254 nm. BrU is converted to uracil with the release of Br-, as shown by UV analysis and high p