Photorearrangements of benzyl phosphites. Stereochemistry at phosphorus
β Scribed by S.Matthew Cairns; Wesley G. Bentrude
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 228 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Photo-Arbuzov Rearrangements of Benzylic Phosphites. Stereochemistry at Migratory Carbon. -The predominant overall stereochemistry in the photo-Arbuzov rearrangement of trans phosphite (I) is retention of configuration. It leads to the cis-phosphonate as a mixture of diastereomers (II) and (III). -(
## Reactions of one diastereomer of a )P-NMe2 compound (La) with alcohols, phenol and amines have been shown by NMR to proceed with initial inversion at phosphorus, but the overall reactions are not stereoselective.