Photorearrangement of N-alkanoyl β-enaminones. Application to the synthesis of α-amino-β,γ-unsaturated acid derivatives
✍ Scribed by Aïcha Amougay; Olivier Letsch; Jean-Pierre Pete; Olivier Piva
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 837 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
A general, stereospecific, synthesis of S,Y-unsaturated a-amino acids using the S-anion derived from aspartic acid is described . S,Y-Unsaturated amino acids have been found to be reversible or irreversible inhibitors of a number of enzymes,' and this has prompted a number of racemic syntheses of th
In previous papers, l-3 we reported the synthesis of a,S-unsaturated N-acyla-amino acid ester (1) by the condensation of ethyl a-oxocarboxylate with amide or by the treatment of N-acetoxy-N-acyl-a-amino acid ester with Et3N. Up to date,