The crystal structure of the title compound, C 12 H 11 ClO 2 , contains intermolecular OÐHÁ Á ÁO and CÐHÁ Á ÁO interactions, linking the molecules to form a three-dimensional framework. The dihedral angle between the cyclopentene plane and the benzene ring plane is 67.00 (7) . CÐHÁ Á Á% interactions
✦ LIBER ✦
Photorearrangement of 4-alkyl-4-alkoxy-2, 5-cyclohexadienones: synthesis of 4-(alkyldimethoxymethyl)cyclopent-2-en-1-ones
✍ Scribed by Arthur G. Taveras Jr.
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 191 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The irradiation of 4-alkyl-4-alkoxy-2,5-cyclohexadienones 3a-d at 366 nm in methanol -af ords 4-(alkyldimethoxymethyl)cyclopent-2-en-l-ones 5a-d.
--
📜 SIMILAR VOLUMES
2-[(4-Chlorophenyl)hydroxymethyl]cyclo
✍
Huo, Fangjun ;Yin, Caixia ;Yang, Pin
📂
Article
📅
2004
🏛
International Union of Crystallography
🌐
English
⚖ 291 KB
2-[Hydroxy(4-nitrophenyl)methyl]cycl
✍
Huo, Fangjun ;Yin, Caixia ;Guo, Wei ;Xia, Chizhong
📂
Article
📅
2004
🏛
International Union of Crystallography
🌐
English
⚖ 133 KB
Reactions of organolithium reagents with
✍
Alfred Fischer; George N. Henderson
📂
Article
📅
1980
🏛
Elsevier Science
🌐
French
⚖ 273 KB
A novel synthesis of 4-alkyl-4-(4-methox
✍
Louis D. Schulte; Reuben D. Rieke
📂
Article
📅
1988
🏛
Elsevier Science
🌐
French
⚖ 268 KB
The dianion formed by reduction of (q6:q6-4,4'-dimethoxybiphenyl)-[Cr(C0)3]2 reacts with electrophiles such as methyl or ethyl triflate or ally1 tosylate at -78 oC followed by CF3CO2H and 12 to form 4-alkyl-4-(4-methoxyphenyl)cyclohex-2en-1 -ones.
Heterocyclization of 1-alkyl-4-chlorobut
✍
R. A. Gadzhily; V. M. Fedoseev; N. A. Netkacheva; Ch. N. Akhmedov; M. Sh. Sultan
📂
Article
📅
1989
🏛
Springer US
🌐
English
⚖ 47 KB
Synthesis of 2-Alkyl-1,2,4-benzotriazin-
✍
D. L. Lipilin; A. M. Churakov; Yu. A. Strelenko; V. A. Tartakovsky
📂
Article
📅
2006
🏛
John Wiley and Sons
⚖ 17 KB
👁 1 views