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Photoreaction of (RS,SR)-3-Phenyl-6-hepten-2-ol. Benzene-Olefin Cycloadditions as a Synthetic Route to [5.5.5.5] Fenestranes. Part III

✍ Scribed by Jürg Mani; Jung-Hyuck Cho; Rameshchandra R. Astik; Erich Stamm; Peter Bigler; Veronika Meyer; Reinhart Keese


Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
725 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Irradiation of (RS,SR)‐3‐Phenyl‐6‐hepten‐2‐ol (3n) gave the photoproducts 6n10n. Some reactions of 6n and 8n are reported. The regio‐ and diastereoselectivity observed in the photoreaction of substituted 5‐phenylpentenes is discussed with respect to conformational preferences of the compounds to be irradiated.