Photoreaction of Benzophenone with the n-Alkanes: A Model for Biomolecular Reactions of Polymers
β Scribed by Winnik, Mitchell A.; Maharaj, Utam
- Book ID
- 126789551
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 517 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Relative rate constants for the reaction of OH radicals with a series of __n__βalkanes have been determined at 299 Β± 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with __n__βbutane of 2.58 Γ 10^β12^ cm^3^ mo
An error was discovered in the method used for calculating the moments of inertia for the internal rotations in the activated complex. In order to retain good agreement between theory and experiment, it was necessary to change some other molecular parameters of the activated complex. The following c