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Photopolymerization of chiral crystals. 1. The planning and execution of a topochemical solid-state asymmetric synthesis with quantitative asymmetric induction

โœ Scribed by Addadi, Lia; Lahav, Meir


Book ID
126436692
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
851 KB
Volume
100
Category
Article
ISSN
0002-7863

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Diastereo- and Enantioselective ฮด-H Abst
โœ Hermann Irngartinger; Peter Walter Fettel; Volker Siemund ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 175 KB ๐Ÿ‘ 1 views

Due to the matrix effect of the crystal lattice, irradiation of alcohol 2 could be produced, depending on which enantiomorphic form of the chiral crystal was irradiated. As ketone 1 yields 2 diastereoselectively as the main product (97% de). Furthermore, the chiral crystal environment in the ketone