Photophysics of the mixed (phthalocyaninato)(porphyrinato) rare earth [terbium (III) and europium (III)] double- and triple-decker sandwich compounds
✍ Scribed by Xuan Sun
- Book ID
- 116898426
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 417 KB
- Volume
- 158
- Category
- Article
- ISSN
- 0379-6779
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Mixed phthalocyaninato tetrakis(4‐pyridyl)porphyrinato rare earth triple‐decker complexes M~2~(TPyP)~2~(Pc) [M = La (1), Eu (2)] have been prepared by condensation between M(TPyP)acac generated in situ and M(Pc)~2~. Their symmetrical structure (TPyP)M(Pc)M(TPyP) was verified by ^1^H NMR
## Abstract Raman spectroscopic data in the range 500–1800 cm^−1^ for a series of 15 mixed [tetrakis(4‐chlorophenyl)porphyrinato](phthalocyaninato) double‐decker complexes with tervalent rare earths M^III^(TClPP)(Pc) (M = Y, LaLu except Ce and Pm) and intermediate‐valent cerium Ce(TClPP)(Pc) were
## Abstract The half‐sandwich rare‐earth complexes [M^III^(acac)(TClPP)] (M=Sm, Eu, Y; TClPP=__meso__‐tetrakis(4‐chlorophenyl)porphyrinate; acac=acetylacetonate), generated in situ from [M(acac)~3~]⋅__n__ H~2~O and H~2~(TClPP), were treated with 1,8,15,22‐tetrakis(3‐pentyloxy)phthalocyanine [H~2~{P