We presented a calculation of the total and partial decay widths of vibrational ลฝ . predissociation VP of the HeI molecule for low initial vibrational excitations from the 2 ลฝ . lowest van der Waals vdW state with total angular momentum J s 0. A time-dependent golden rule wave-packet method was empl
โฆ LIBER โฆ
Photophysics of He-ICl van der Waals complexes: Excitation to predissociative levels in the B state
โ Scribed by John M. Skene; Marsha I. Lester
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 719 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Fluorescence excltahoo speclra of He-ICI complexes are obtarned for the B 31T,~ (o'= 3)-X '2+( u"= 0) transition. Tlus ~n!ca~~ LhaL wbr?uonal prcxhssocrauon OF Lhe van dcr Waals complex competes effccllvely WUII tie subnanosecond electronic prtiiahon of the bare ICI molecule A lower bound estimate for the wbrauooal prehssociation Lfetime 1s SO+150 Ps Volume 116. number 2,3 CHEMICAL PHYSICS LETTERS
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