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Photophysics of 3-Substituted Benzanthrones: Substituent and Solvent Control of Intersystem Crossing

✍ Scribed by Kapusta, Peter; Machalický, Oldřich; Hrdina, Radim; Nepraš, Miloš; Zimmt, Matthew B.; Fidler, Vlastimil

Book ID: 115467190
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 113 KB
Volume: 107
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp035610a

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## Abstract The solvent effect on a nucleophilic substitution reaction of 2‐ and 4‐chloro‐3,5‐dinitrobenzotrifluoride with substituted anilines was studied in methanol, acetonitrile, and toluene at 25°C. This reaction is of second order, except 2‐chloro‐3,5‐dinitrobenzotrifluoride in toluene shows