We realized and investigated films of zinc-phtalocyanines into poly(methylmethacrylate) (PMMA) for optical limiting applications. The ratio by weight of the compound to the host polymer was 0.083% and 0.15%. Linear optical characterization of films, performed by spectrophotometry, show a low degree
Photophysics and Nonlinear Absorption of Peripheral-Substituted Zinc Phthalocyanines
β Scribed by Li, Yunjing; Pritchett, Timothy M.; Huang, Jiandong; Ke, Meirong; Shao, Pin; Sun, Wenfang
- Book ID
- 115459539
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 821 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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Photophysical and nonlinear optical properties of zinc phthalocyanines (ZnPc) bearing peripheral phenoxy substituents containing different functionalized groups were studied. Fluorescence spectra corresponding to the optical transition S 1 β S 0 are found to be appeared at 684 or 686.4 nm. Z-scan te
## Abstract The effect of substituents on the position and intensity of the electronic absorption and fluorescence spectra of phthalocyanines (Pcs) was examined for 35 Pc compounds. When electronβreleasing groups are bound to four __Ξ±__βbenzo positions of the Pc skeleton, the B and Q bands shift to