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Photophysics and kinetics of naphthopyran derivatives, part 3: A general procedure to uniquely identify the kinetic and spectroscopic parameters of ABC(2k,2ϕ) systems and application to naphthopyran reactions

✍ Scribed by M. Maafi; R. G. Brown

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
199 KB
Volume
38
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A new procedure has been developed with the aim of determining the kinetic and spectroscopic parameters of any photochemical systems of the generic ABC(2__k__,1ϕ) and ABC(2__k__,2ϕ) types. General expressions of the colorability and the equilibrium concentration ratio of two (of the three involved) species at a photostationary state or a state of thermal equilibrium have been derived. The procedure has been successfully applied to achieve unique identifiability for the seven sequences of the ABC(2__k__,1ϕ and 2ϕ) type that may represent naphthopyran dynamics. It is demonstrated that the reactivity of this particular compound is certainly described by a higher kinetic level than those (three or four reaction steps) considered in the present study. © 2006 Wiley Periodicals, Inc. Int J Chem Kinet 38: 421–430, 2006

📜 SIMILAR VOLUMES

Erratum: “Photophysics and kinetics of n
Erratum: “Photophysics and kinetics of naphthopyran derivatives, Part 3: A general procedure to uniquely identify the kinetic and spectroscopic parameters of ABC(2k,2ϕ) systems and application to naphthopyran reactions”, Int J Chem Kinet 2006, 38, 421
📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 41 KB

## Abstract The original article to which this Erratum refers was published in International Journal of Chemical Kinetics 38 (7) 2006, 421–430.

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