Photophysics and Crystal Structure of a Europium(III) Cryptate Incorporating 3,3‘-Biisoquinoline-2,2‘-dioxide
✍ Scribed by Gawryszewska, P.; Jerzykiewicz, L.; Pietraszkiewicz, M.; Legendziewicz, J.; Riehl, J. P.
- Book ID
- 120637591
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 115 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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## Abstract __A detailed photophysical study of [Eu⊂(biqO__~__2__~__.2.2)(CF__~__3__~__SO__~__3__~__)](CF__~__3__~__SO__~__3__~__)__~__2__~__⋅CH__~__3__~__CN⋅H__~__2__~__O (Eu⊂1) and two other types of cryptates incorporating three 3,3′‐biisoquinoline‐2,2′‐dioxide units has been performed. Structur
The spectroscopic and photophysical properties of [ Eu3+ c 2.2.11 have been investigated. High-resolution emission spectra in aqueous solution are compatible with the presence of only one Eu-containing species with Czy symmetry. The emission quantum yields indicate that the conversion of the charge-