Photophysical properties of σ–π-conjugated alternating oligothienylene–oligosilylene polymers

✍ Scribed by Heqing Tang; Lihua Zhu; Yutaka Harima; Kazuo Yamashita; Joji Ohshita; Atsutaka Kunai

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 162 KB
• Volume: 37
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/(sici)1099-0488(19990801)37:15<1873::aid-polb11>3.0.co;2-t

✦ Synopsis

UV-visible absorption and fluorescence properties of three series of -conjugated polymers (copolymers of alternative oligothienylene and oligosilylene units) have been studied in dioxane solution. The energies of the absorption maximum, fluorescence maximum, and the 0 -0 transition are found to be linearly dependent on the reciprocal of the number of thiophene rings in the repeating unit of the polymer chain, but almost independent of the silicon atom number. The --conjugation in the polymers results in red shift in the absorption and fluorescence maxima, higher fluorescence quantum yields, and longer fluorescence lifetimes of the polymers, with respect to their corresponding analogous ␣-oligothiophenes.