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Photophysical properties and applications of Re(I) and Re(I)–Ru(II) carbonyl polypyridyl complexes

✍ Scribed by Anthony Coleman; Claire Brennan; Johannes G. Vos; Mary T. Pryce

Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 994 KB
Volume: 252
Category: Article
ISSN: 0010-8545
DOI: 10.1016/j.ccr.2008.07.001

No coin nor oath required. For personal study only.

✦ Synopsis

This review focuses on the photophysical properties of rhenium(I) tricarbonyl moieties of the type [Re(CO) 3 (NN)L] (where NN = polypyridyl ligand and L = chloride or nitrogen donor atom) and their importance to the area of inorganic chemistry. Processes such as electron transfer, energy transfer and photodissociation are also highlighted. The second aspect of this review highlights the photophysical properties of dinuclear ruthenium(II)-rhenium(I) complexes, with particular emphasis on the importance of the electronic properties of the bridging ligand between the metal centres. Applications of such complexes include CO 2 reduction, DNA cleavage, and biological labels for various therapeutic, diagnostic, and mechanistic applications.

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