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Photooxygenation of vinylstannanes: tin-substituted allylic hydroperoxides through the regio- and diastereoselective ene reaction with singlet oxygen

✍ Scribed by Adam, Waldemar; Klug, Peter


Book ID
126118256
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
649 KB
Volume
58
Category
Article
ISSN
0022-3263

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Regio- and diastereoselective ene reacti
✍ Adam, Waldemar ;Nestler, Bernd πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 319 KB

## Abstract Photooxygenation of methyl (__E__)‐ and (__Z__)‐2‐methyl‐4‐phenyl‐2‐pentenecarboxylates (__E__‐1, __Z__‐1) afforded the hydroperoxy esters (__R__\*,__S__\*)‐2a and (__S__\*,__S__\*)‐2b through regiospecific and diastereo‐selective ene reaction of singlet oxygen at the α‐methyl group wit