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Photooxygenation of the CN bond: a mild new method for oxidative CC cleavage

✍ Scribed by Nüket Öcal; Lovelle M. Yano; Ihsan Erden

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
132 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Upon photooxygenation in the presence of base, a-oximinocarbonyl compounds undergo clean oxidative C C cleavage giving rise to mixtures of esters and acids. The mechanism of these reactions involves some unusual peroxidic intermediates, including a 2,3,5-trioxapentanes.

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