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Photonitration of phenols by tetranitromethane under visible light

✍ Scribed by Seltzer, Stanley; Lam, Eric; Packer, Lester

Book ID
127386907
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
282 KB
Volume
104
Category
Article
ISSN
0002-7863

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During the irradiation of phenol (1) with 15 N-enriched tetranitromethane in acetonitrile, and during the reaction of 1 with 15 N-enriched nitric acid and nitrous acid, emission due to the nitration products o-and p-nitrophenol (2a, 2b) is observed in the 15 N-NMR spectra. The CIDNP effects are buil