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Photon-induced processes for chemisorbed O2 on Pd(111): effect of light polarization

✍ Scribed by Jun Yoshinobu; Xingcai Guo; John T. Yates Jr.


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
356 KB
Volume
169
Category
Article
ISSN
0009-2614

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✦ Synopsis


The photon-induced &sorption and dissociation of OZ chemisorbed on Pd( 111) have been studied using s-and p-polarized light (hv= 1.4-5.4 eV). Post-irradiation temperature-programmeddesorption (TPD) measurements have been used to follow the 02 photodesorption and O2 photodissociation processes. Both O2 photodesorption and dissociation are enhanced by p-polarized light compared to s-polarized light.