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Photomodulation of the Chiroptical Properties of New Chiral Methacrylic Polymers with Side Chain Azobenzene Moieties

✍ Scribed by Luigi Angiolini; Renato Bozio; Loris Giorgini; Danilo Pedron; Giovanni Turco; Alessandro Daurù


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
137 KB
Volume
8
Category
Article
ISSN
0947-6539

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Synthesis and chiroptical properties of
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Experimental part ## Chemicals, monomers and models Methacryloyl chloride (Aldrich) was distilled (b. p. 95 8C) under inert atmosphere in the presence of traces of 2,6-ditert-butyl-p-cresol as polymerization inhibitor just before

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Novel optically active polymethacrylates, namely poly[(S)-3-methacryloyloxy-1-(4-azobenzene)pyrrolidine] and poly[(S)-3-methacryloyloxy-1-(4Ј-nitro-4-azobenzene)pyrrolidine], have been synthesized by radical polymerization of the corresponding monomers, prepared in turn through a synthetic route pre

Optically active polymers bearing side-c
✍ Luigi Angiolini; Daniele Caretti; Carlo Carlini; Elisabetta Salatelli 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 688 KB

## Abstract Novel optically active monomers such as __trans__‐(__S__)‐4‐(2‐methacryloylaminopropano‐ylamino)azobenzene, __trans__‐(__S__)‐4‐(2‐methacryloyloxypropanoylamino)azobenzene, and __trans__‐(__S__)‐4‐(2‐acryloylaminopropanoylamino)azobenzene have been prepared and homopolymerized by free r