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Photolytic generation of carbon radicals from barton esters: Recent developments

✍ Scribed by Derek H.R. Barton; Joseph Cs. Jaszberenyi; Dagang Tang

Book ID: 104215806
Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 270 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)79161-1

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✦ Synopsis

Acyl derivatives of thiohydroxamic acids1 and hydroxamic acids2 are useful precursors of various carbon-centered (mostly alkyl or substituted alkyl). nitrogencentered, oxygen-centemd and other radicals.~ The most often used and most versatile examples are various O-acyl derivatives 2 (Barton esters) of the thiohydroxamic acid N-hydroxy-2-thiopyridone

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