𝔖 Bobbio Scriptorium
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Photolytic determination of SO4- rate constants

✍ Scribed by Ivan Kraljić


Book ID
103113607
Publisher
Elsevier Science
Year
1970
Weight
468 KB
Volume
2
Category
Article
ISSN
0020-7055

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📜 SIMILAR VOLUMES


Rate constants for reactions of SO4˙− ra
✍ S. Padmaja; Z. B. Alfassi; P. Neta; R. E. Huie 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 341 KB 👁 1 views

Rate constants have been measured for the reactions of the sulfate radical, SO4'-, with alkanes, alkenes, alcohols, ethers, and amines in 95% acetonitrile solution. The rate constants were in the range of lo6 L mol-l s-l for the abstraction reactions and lo7 -lo9 L mol-' s-l for the addition and ele

Rate constants for hydrogen abstraction
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Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M