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Photolytic behaviour of tricarbonyl[(1,2,5,6-η)-cycloocta-1,5-diene]iron in solution and low-temperature matrices

✍ Scribed by Friedrich-Wilhelm Grevels; Werner E. Klotzbücher; Graham Russell; Kurt Schaffner


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
630 KB
Volume
114
Category
Article
ISSN
0165-0513

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✍ Nobuyuki Akai; Satoshi Kudoh; Munetaka Nakata 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 217 KB

Reversible photoisomerization of 2,3,6,7-tetracyano-1,4,5,8-tetraazanaphthalene (TTN) in low-temperature rare-gas matrices was investigated by electronic absorption and Fourier transform infrared (FTIR) spectroscopies aided bydensity-functional-theory (DFT) calculations. The reactant, TTN, was found