Synthesis and photolysis of some carbohy
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Robert J. Ferrier; Peter C. Tyler
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Article
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1985
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Elsevier Science
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English
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Several attempts to abbreviate our earlier syntheses of the prostaglandin intermediates 4 and 5 by photocyclisation of carbohydrate-based 1,6-dienes (15-18, 20, 22) did not yield the required bicyclo[3.2.0]heptane derivatives. Photolysis of 7-O-tert-butyldimethylsilyl-1,3,4,5,8,9-hexadeoxy-6-O-metho