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Photolysis of some 1,6-dienes. Total synthesis of (.+-.)-.alpha.-bourbonene

โœ Scribed by Brown, Morris


Book ID
120241670
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
657 KB
Volume
33
Category
Article
ISSN
0022-3263

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Several attempts to abbreviate our earlier syntheses of the prostaglandin intermediates 4 and 5 by photocyclisation of carbohydrate-based 1,6-dienes (15-18, 20, 22) did not yield the required bicyclo[3.2.0]heptane derivatives. Photolysis of 7-O-tert-butyldimethylsilyl-1,3,4,5,8,9-hexadeoxy-6-O-metho