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Photolysis of s-phenyl thiobenzoates in various media

โœ Scribed by Jing-Jing Su; Guang-Song Dai; Shi-Kang Wu

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
416 KB
Volume
83
Category
Article
ISSN
1010-6030

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โœฆ Synopsis

The photolysis of two s-phenyl thiobenzoates containing different substituent groups was investigated in benzene solution and on thin-layer chromatography plates (silica). The photolytic products include benzaldehyde, thiophenol, diphenyldisulphide, diphenylsulphide, 1-l'-biphenyl and two photo-Fries rearrangement products, oriho-mecaptobenzoylbenzene and para-mercaptobenzoylbenzene.

The results indicate that the distribution of the photolytic products strongly depends on the medium. Cage effects and external magnetic field effects are discussed. The photolytic reaction of s-phenyl thiobenzoates proceeds through the excited triplet state.

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