✍ Scribed by R. Simonaitis; S. Braslavsky; Julian Heicklen; M. Nicolet
No coin nor oath required. For personal study only.
The photolysis of 03 at 3 130 A and 25°C has been studied in the presence of a large excess of NaO to react with any O('D) atoms produced. From the N2 produced, the quantum efficiency for O('D) production was found to be 0.50 f 0.03.
📜 SIMILAR VOLUMES
The photolysis of SO? at 3130 A, FWHM = 165 d, and 22°C has been investigated in the presence of cis-and trans-2-pentene. Quantum yields for the SO, photosensitized isomerization of one isomer to the other have been made for a variation in the [SO,]/[C,HIo] ratio of 3.41-366 for cis-2-C5HI0 and of 1
The method of chemical difference was utilized to accurately deterornine the relative importanceoof all the reaction steps in the direct photolysis of NzO at 21 39 A (25" and 250°C) and 1849 A (25" C), as well as in the Hg6('Pl)-sensitized photolysis of Nz0 at 1849 A (25°C). (1) NzO + hv or Hg6('PI)
The photolysis of pure NzO, NzO and Nz, and N20 and C3Hs mixtures at 1470 A and room temperature has been studied to determine the relative importance of the primary processes. The results are TI) where +{ O('D) ] = 0.515 represents both the O(lD) produced in the primary act and that produced by co