Photolysis of Nitrite Esters in Solution. III. Photochemistry of Primary, Secondary and Tertiary Alkyl Nitrites
โ Scribed by Kabasakalian, Peter.; Townley, Edward R.; Yudis, Milton D.
- Book ID
- 120513209
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 609 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Although our pyrolytic studies of five alkyl nitrites (RONO) have shown that it is possible to determine precise, acceptable values for k 1: (0 RONO -RO + NO we have been uncertain about the mechanism for the first order production of nitroxyl from primary and secondary nitrites. Nitroxyl could ari
The alkyl nitrites, C 2 H 5 0 N 0 , n -C 3 H 7 0 N 0 , n-C4HgON0, and i -C 4 H g O N 0 were photolyzed at 23ยฐC in the presence of "NO at 366-nm incident radiation. The quantum yields of the corresponding isotopically-enriched alkyl nitrites were measured by mass spectrometry. The results indicated t