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Photolysis of Methylcobalamin: Identification of the Relevant Excited States Involved in Co−C Bond Scission

✍ Scribed by Jaworska, Maria; Lodowski, Piotr; Andruniów, Tadeusz; Kozlowski, Pawel M.


Book ID
120508777
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
116 KB
Volume
111
Category
Article
ISSN
0022-3654

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CO-Bond Cleavage of Esters with a Naphth
✍ Xichen Cai; Masanori Sakamoto; Minoru Yamaji; Mamoru Fujitsuka; Tetsuro Majima 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 1 views

## Abstract A CO‐bond cleavage of esters having a naphthyl group, NpCO‐OR and RCO‐ONp (Np=α‐ and β‐naphthyl (^α^Np and ^β^Np, respectively), R=Ph and Me), was found during the two‐color two‐laser flash photolysis in acetonitrile. The CO‐bond cleavage occurred when NpCO‐OR and RCO‐ONp were excited