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Photolysis of Formaldehyde at 1470 and 1236 Å

✍ Scribed by Glicker, S.

Book ID
121800639
Publisher
American Institute of Physics
Year
1971
Tongue
English
Weight
643 KB
Volume
54
Category
Article
ISSN
0021-9606

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The photolysis of pure NzO, NzO and Nz, and N20 and C3Hs mixtures at 1470 A and room temperature has been studied to determine the relative importance of the primary processes. The results are TI) where +{ O('D) ] = 0.515 represents both the O(lD) produced in the primary act and that produced by co

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Hz0 + izu(h = 1470 ii, --) HZ + O('D) , Hz0 + It&', = 1470 A) + H + OH with the Hz yield of the fust process accounting for 23% of the overall H2 prodxtion. ike qwntum yield of this process is estimated to be 0.08 by using 02 as a scavenger for H-atcns. Secondary re;lctioris involving the photolyti