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Photolysis of Diazo(pentamethyldisilanyl)methyl Ketones in the Presence of Carbonyl Compounds: Trapping of the Acylsilene Intermediates

✍ Scribed by Maas, Gerhard ;Alt, Mechthild ;Schneider, Klaus ;Fronda, Antonio


Book ID
102789075
Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
679 KB
Volume
124
Category
Article
ISSN
0009-2940

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## Abstract Photolysis of trifluoromethyl ketones (TFMKs) 1a–1e __versus__ the non‐fluorinated ketones 2a–2b in the presence of radical initiators by electron paramagnetic resonance spectroscopy has been studied for the first time. The transient radicals generated after irradiation of the ketones w