Vacuum oltraviolet photclysis of N20 isolated in ir,-matrices at 4 K gives direct luminescent evidence for the pkotodissocktive piodbction of both O("S) and X(\*D). The matrix icsults zrc compared to reiative atomic quantum yields meas!xed in the gels phase.
Photolysis of asym-N2O4 (ONONO2) isolated in an argon matrix at 11 K
โ Scribed by Hiroshi Bandow; Hajime Akimoto; Sadachika Akiyama; Takahiro Tezuka
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 431 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Rewimd 6 June 1984: in lin,d for111 77 August 1984 411 unstable ixomcr of dinitrogen tctroudc. 0NON02 hsym-N204), UVF photohzcd in an Ar matrix .I[ 1 I K 31436 .md 25 10 nw Asyrn-to sym-X204 (OzNNOz) isomcriwtion wag the major process at 436 mn; other products observed where NO. cis-(NO)z, ~sym-N~O3 (OzNNO) md NzOs. lrradi&ion of asym-NzOq at 2510 nm induced no reaction. CHEXllCAL PHYSICS LETTERS
๐ SIMILAR VOLUMES
Two SCII~S of cmwon bands wcrc obscrvcd for the CSz/Ar (I 100-500) system a1 15 K with cultatlon at 257 3 nm They are asslgncd IO B %j -?( 3X-g and U" 311u -. X jri of S2z which was formed by photodlssoclatlon of CS2, CS2 + lw -+ CS + S, followed by recombmauon of two S atoms The 8" 3~,, state b3s b