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Photolysis of alkyl azides. Evidence for a nonnitrene mechanism

โœ Scribed by Kyba, Evan P.; Abramovitch, Rudolph A.


Book ID
121390005
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
865 KB
Volume
102
Category
Article
ISSN
0002-7863

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A COz TEA laser has been used to photolyze dilute samples of various aIky1 halides in helium. The mechanism of the high intensity infrared photolysis of these moiecules involves the decomposition of moiecules into molecular or radical fragments. The reaction pathway is always dissociation into the l