## Crystals of the tetrasaccharide, (2,3,4,6-tetra-0acetyl-fi-D-ghxopyranosyl~-(1 + 3)-[2,3,4,6-tetra-O-acetyI+LD-gIucopyranosyI-(1 --t 6)]-(2,4-di-0-acetyl-g\_D-glucopyranosyl)-1 --) 3)-1,2,4,6-tetrad-acetyl$?-n-ghicopyranose, belong to tge monoclinic system, space group P2,, with a = 12.709(4),
✦ LIBER ✦
Photolyse stereospecifique d'(oxo-3butyl)-tetra-O-acetyl-2, 3, 4, 6-β-D-glucopyranoside en spiro-C-1-sucre
✍ Scribed by Georges Remy; Louis Cottier; Gérard Descotes
- Book ID
- 104238192
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 198 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
26'C pour 4 et 24'C pour 7 , 8a et 8b ; 25'C pour 8~ et 20°C pour 8d .
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Two independent molecules comprise the asymmetric unit of the title compound, C 15 H 19 F 3 O 12 S, which was synthesized by reacting 1,3,4,6-tetra-O-acetyl--d-mannopyranose with trifluoromethanesulfonic anhydride. In one molecule three F atoms and one O of the -SO 2 CF 3 side chains are disordered