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Photolabeling of dextransucrase from Streptococcus sanguis with p-azidophenyl α-d-glucopyranoside

✍ Scribed by Susan F. Kobs; Robert M. Mayer


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
567 KB
Volume
211
Category
Article
ISSN
0008-6215

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✦ Synopsis


Dextransucrase from Streptococcus sanguis ATCC 10558 was photolabeled using p-azidophenyl alpha-D-glucopyranoside with an apparent rate constant of inactivation of 1.40 min-1. The dissociation constant for this compound, which acts as an acceptor molecule in the enzymatic reaction, is 90 microM. Apparently two acceptor binding sites exist on dextransucrase as shown by (i.) photolabeling the enzyme with p-azidophenyl-alpha-D-[5,6-3H]glucopyranoside and (ii.) fluorescence titration experiments.