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Photoisomerization of the B 20 H 18-2 Ion

✍ Scribed by Hawthorne, M. Frederick; Pilling, Richard L.

Book ID: 120300022
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 236 KB
Volume: 88
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00968a044

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Das bekannte polyedrische Boran-Anion [B 20 H 18 ] 2À 1, das im folgenden trans-[B 20 H 18 ] 2À genannt wird, und sein Photoisomer iso-[B 20 H 18 ] 2À 2 [2] wurden erstmals in den sechziger Jahren synthetisiert, kurz nachdem die ersten polyedrischen Borane beschrieben worden waren. Die elektrophile