Photoisomerization of dimyristoylindigo: rates in various solvents
β Scribed by G.R. Seely; E.R. Shaw
- Book ID
- 103493850
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 794 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The dependence of the activation energy for trans-stilbene photoisomerization on solvent permittivity has been determined in n-alcohols via fits of the isomerization rates across the alcohol series at constant solvent permittivity to Kramers expression. The results of this procedure indicate that th
The photolsomcri7dtlon of tllioindlgos 1~ been invcstgatcd mainly \IO fluorcsccnce qumturn yield and hfctirnc I~~CJsurcmcnts over 3 lnrgc tcmpcr.ltun: range. A model has been proposed from which various rate conctmts and activation encgicc could bc detcrrnincd
Trichloromethylperoxyl radicals were produced by pulse radiolysis of air saturated solutions containing CC1,. The rate constants for the reaction of CCI,O, radicals with zinc tetraphenylporphyrin (ZnTPP) were determined in various solvents. They were found to vary between 3 x lo7 and 3 x 1 0 ' M-' s