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Photoionization of inner valence electrons in gaseous NO: a synchrotron radiation study

โœ Scribed by H.-J. Freund; H. Kossmann; V. Schmidt

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
533 KB
Volume
137
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

We report photoelectron spectra of the outer and, m particular, the inner valence electron region of gaseous NO for several photon energies between 45 and I10 eV. The spectra are measured at the quasi magic angle, so that the electron distribution curves represent the variation of the cross sectlon independent of the p parameter. We find 16 bands in the inner valence region which can be tentatively correlated to various shake-up excitations. On the basis of published theoretical work, a comparison is made with spectra taken with soft X-ray excitation.

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The photoelectron spectrum of gaseous COz is investigated in the inner valence electron region, between 20 and 45 eV binding energies for photon energies between 40 and 100 eV using synchrotron radiation. The branching ratio for inner valence ionizations increases considerably as a function of photo