Photoionization of dimethyl ether and diethyl ether
β Scribed by R. Botter; J.M. Pechine; H.M. Rosenstock
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 941 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0020-7381
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Absolute rate coeficients for the reactions of the hydroxyl radical with dimethyl ether i k , ) and diethyl ether ( k 2 ) were measured over the temperature range 295-442 K. The rate coefficient data, in the units cm3 molecule s-l, were fitted to the Arrhenius equationsk,(T) = (1.04 2 0.10) x 10-"ex
## Abstract Information is given as to the rates of peroxidation of diethyl ether and diβ__iso__propyl ether under normal laboratory conditions of storage, both with and without inhibitors. Diβ__iso__propyl ether peroxidizes in daylight at least twice as rapidly, and in the dark several times as ra
Comparative studies o/ the combustion o/ diethyl ether, pentane and acetaldehyde have been carried out over all the oxidation stages that lead to ignition. The relative reactivities of diethyl ether and pentane have been shown to be vastly different from those reported previously. Detailed analyses
vs), 1156 (vs), 822 (m), 728 (m), and 547 (m) cm-l[3al. The vapor pressure curve accords with the equation log p = -1464/T+ 8.54 (Trouton constant 25.9).
cyclohexane q diethyl ether g and benzene q diethyl ether g at standard atmospheric pressure over the temperature range 353.2 K to 423.2 K. The non-ideality of the cyclohexane and benzene was fitted using the Kihara potential, and that of the diethyl ether using the Ε½ Stockmayer potential. Cross-ter