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Photoionisation mass spectra of volatile derivatives of short peptides and appearance potentials of their characteristic ions

โœ Scribed by V. M. Orlov; Ya. M. Varshavsky; A. I. Miroshnikov


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
604 KB
Volume
9
Category
Article
ISSN
1076-5174

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The Negative Ion Mass Spectra of [Mโ€“H]โˆ’
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The collision-induced spectra of [M-H] -ions of peptides containing Asp and Asn residues exhibit characteristic backbone cleavage ions produced via the enolate anions of the Asp or Asn side chains. Such reactions do not occur from the analogous Glu or Gln residues. Asp and Asn residues may be distin