Photoinitiation of Acrylate Polymerization with (Arene)chromium Complexes
✍ Scribed by E. Peter Kündig; Long-He Xu; Mikhail Kondratenko; Allan F. Cunningham Jr.; Martin Kunz
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 238 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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The kinetics of photoinitiated polymerization of six analogous di(meth)acrylates and diacrylates was analysed according to the autocatalytic model (where is polymerization rate, p is conversion degree, R p \ kpm(1 [ p)n R p k is reaction rate constant and m and n are exponents), in order to Ðnd the
## Abstract The polymerization of methyl methacrylate and butyl acrylate initiated by azo‐bis‐isobutyronitrile in the presence of metal‐containing monomers (__p__‐methylstyrene‐, stilbene‐ and α‐methylstyrene‐chromiumtricarbonyl) was studied. Kinetic parameters (i.e. the decrease in the autoacceler
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract For Abstract see ChemInform Abstract in Full Text.