A series of aryl 1-propenyl ethers (ArPE) were prepared by the isomerization of the corresponding allyl aryl ethers (AArE) and used for photoinduced cationic polymerization studies. Attempted polymerization reactions using diaryliodonium salts as photoinitiators generally resulted in low yields of o
Photoinitiated cationic oligomerization of terminal and internal epoxides
โ Scribed by Siegfried Warwel; Eberhard Fehling; Michael Kunz
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 165 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1438-7697
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๐ SIMILAR VOLUMES
A series of epoxy alcohols were prepared by simple, straightforward methods. These compounds were very reactive monomers that polymerized rapidly on UV irradiation in the presence of cationic photoinitiators. The kinetics of the cationic photopolymerization of these monomers were studied with diaryl
## Abstract For Abstract see ChemInform Abstract in Full Text.
A kinetic study of the independent and simultaneous photoinitiated cationic polymerization of a number of epoxide and vinyl (enol) ether monomer pairs was conducted. The results show that, although no appreciable copolymerization takes place, these monomers undergo complex interactions with one anot