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Photoinduced switching of metal complexation by quinolinospiropyranindolines in polar solvents

โœ Scribed by Collins, Greg E.; Choi, Ling-Siu; Ewing, Kenneth J.; Michelet, Veronique; Bowen, Corinne M.; Winkler, Jeffrey D.


Book ID
120644377
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
87 KB
Volume
4
Category
Article
ISSN
1359-7345

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โœ Corinne Le Borgne; Martial Chabanel ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 557 KB

Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe