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Photoinduced ring expansion of a cyclopropyliron .sigma.-complex to a metalacyclopentenone: an example of alkyl group rearrangement from carbon to iron to generate a carbene complex

✍ Scribed by Lisko, James R.; Jones, W. M.


Book ID
127058613
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
421 KB
Volume
4
Category
Article
ISSN
0276-7333

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Insertion of Fischer carbene complexes i
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The reaction of 4-X-5-alkylthio-3H-1,2-dithiole-3-thione (1) with Fischer carbene complexes (2) gives, as a main product, cyclohexa dithiine derivatives due to insertion of the carbene ligand into the C3 C4 bond of the heterocycle. The reaction takes place with 1 where the alkyl substituents in posi