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Photoinduced reduction of group 16 heteroatom compounds with the aid of samarium diiodide

✍ Scribed by Akiya Ogawa; Syoji Ohya; Mikio Doi; Yukihito Sumino; Noboru Sonoda; Toshikazu Hirao

Book ID
104259734
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
126 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

A novel photoinduced reduction of group 16 heteroatom compounds such as organic selenides, tosylates, and tellurides has been developed. In particular, organic selenides, which can not be reduced with Sml 2 in the dark (or even in the presence of lIMPA), undergo reductive cleavage efficiently by using the S,d2-hv system.

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