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Photoinduced reactions. VII. The photochemical formation of the ground-state reactions of bicyclo[2.1.0]pentan-2-one

✍ Scribed by Matsuura, Teruo.; Ogura, Katsuyuki.


Book ID
126111141
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
944 KB
Volume
89
Category
Article
ISSN
0002-7863

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The oxidation of bicyclo[2.1.0]pentane by isolated dimethyldioxirane and by the more powerful methyl(trifluoromethyl)dioxirane, affords selectively, the corresponding endo-2 alcohol along with the 2,3-diol in high yield, and no rearrangement products; this suggests that a concerted O-insertion mecha