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Photoinduced radical polymerization of styrene derivatives via their cation radicals

✍ Scribed by Tetsuya Gotoh; Masahide Yamamoto; Yasunori Nishijima

Book ID: 104692625
Publisher: Springer
Year: 1980
Tongue: English
Weight: 261 KB
Volume: 2
Category: Article
ISSN: 0170-0839
DOI: 10.1007/bf00266714

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✦ Synopsis

It was found that radical polymerization occurs when the mixture of ~-methoxystyrene and styrene in the presence of electron acceptors is photoexcited in basic solvents.

Concomitantly, p_-methoxystyrenestyrene co-dimers: trans-l-(4'-methoxyphenyl)-2-phenylcyclobutane and l-(4-~-methoxyphenyl)-l,2,3,4-tetrahydronaphthalene are produced.

From the results of some polymerization runs and the co-dimer structure, it is considered that the linear co-dimer cation radical is the common precursor for both radical polymerization and cationic dimerization, and the radical polymerization is initiated by its radical end.

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