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Photoinduced Intramolecular Electron Transfer in Ruthenium and Osmium Polyads: Insights from Theory

✍ Scribed by Ciofini, Ilaria; Lainé, Philippe P.; Bedioui, Fethi; Adamo, Carlo

Book ID
120285799
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
500 KB
Volume
126
Category
Article
ISSN
0002-7863

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Photoinduced energy- and electron-transf
Photoinduced energy- and electron-transfer processes in dinuclear ruthenium(II) and/or osmium(II) complexes connected by a linear rigid bis-chelating bridge
✍ Luisa de Cola; Vincenzo Balzani; Francesco Barigelletti; Lucia Flamigni; Peter B 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 835 KB

## Abstract A rigid and linear bridging ligand containing two 4,5‐diazafluorene chelating units separated by an adamantane spacer (diazf‐a‐diazf) has been synthesized and its dinuclear complexes [(bpy)~2~Ru(diazf‐a‐diazf)Ru(bpy)~2~]^4+^ (Ru^II^ · FAF · Ru^II^), [(bpy)~2~Os(diazf‐a‐diazf)Os(bpy)~2~]